dc.contributor.author | Udachin, KA | |
dc.contributor.author | Senturk, OS | |
dc.contributor.author | Sterenberg, BT | |
dc.contributor.author | Ozdemir, U | |
dc.contributor.author | Sarikahya, FU | |
dc.contributor.author | Sert, S | |
dc.contributor.author | Ercag, A | |
dc.date.accessioned | 2021-03-05T13:41:52Z | |
dc.date.available | 2021-03-05T13:41:52Z | |
dc.date.issued | 2003 | |
dc.identifier.citation | Sert S., Ercag A., Senturk O., Sterenberg B., Udachin K., Ozdemir U., Sarikahya F., "Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)CP] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT) and the crystal structure of [W(CO)(5)(DTTT)]", POLYHEDRON, cilt.22, ss.1689-1693, 2003 | |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_b37458ec-83ac-4cb7-863c-f9760e0ec52c | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/119522 | |
dc.identifier.uri | https://doi.org/10.1016/s0277-5387(03)00309-7 | |
dc.description.abstract | Five new complexes, [M(CO)(5)(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)(4)Br(DTTT)] (4) and [Mn(CO)(2)Cp(DTTT)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)(6)] (M = Cr, Mo and W), [Re(CO)(5)Br], and [Mn(CO)(3)Cp] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT). The complexes have been characterized by elemental analysis, mass spectrometry, FTIR, H-1 and C-13{H-1} NMR spectroscopy. The spectroscopic studies show that DTTT behaves as a monodentate ligand coordinating via the sulfur (C=S) donor atom in 1-5. An X-ray diffraction study Of [W(CO)(5)(DTTT)] (3) confirms that the tungsten adopts a distorted octahedral geometry with local C-4nu symmetry. (C) 2003 Elsevier Science Ltd. All rights reserved. | |
dc.language.iso | eng | |
dc.subject | Sıvı Kristaller ve Sıvı Kristal Polimerler | |
dc.subject | Temel Bilimler | |
dc.subject | İnorganik Kimya | |
dc.subject | KİMYA, İNORGANİK VE NÜKLEER | |
dc.subject | Kimya | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | KRİSTALLOGRAFİ | |
dc.subject | Fizikokimya | |
dc.title | Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)CP] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT) and the crystal structure of [W(CO)(5)(DTTT)] | |
dc.type | Makale | |
dc.relation.journal | POLYHEDRON | |
dc.contributor.department | , , | |
dc.identifier.volume | 22 | |
dc.identifier.issue | 13 | |
dc.identifier.startpage | 1689 | |
dc.identifier.endpage | 1693 | |
dc.contributor.firstauthorID | 169018 | |