dc.contributor.author | Ozdemir, Namik | |
dc.contributor.author | Ulkuseven, Bahri | |
dc.contributor.author | Bal-Demirci, Tuelay | |
dc.contributor.author | Soylu, Mustafa Serkan | |
dc.contributor.author | Guveli, Suekriye | |
dc.date.accessioned | 2021-03-05T19:21:10Z | |
dc.date.available | 2021-03-05T19:21:10Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | Guveli S., Ozdemir N., Bal-Demirci T., Soylu M. S. , Ulkuseven B., "Hydrogen-bonded and -stacked nickel(II) thiosemicarbazone complexes: Synthesis, spectral and structural studies", TRANSITION METAL CHEMISTRY, cilt.44, ss.115-123, 2019 | |
dc.identifier.issn | 0340-4285 | |
dc.identifier.other | av_cedcda59-0cab-4b96-b5a4-7e62593d5d1a | |
dc.identifier.other | vv_1032021 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/136834 | |
dc.identifier.uri | https://doi.org/10.1007/s11243-018-0275-8 | |
dc.description.abstract | Mixed ligand Ni(II) complexes were synthesized from triphenylphosphine and S-methyl- or S-ethyl-isothiosemicarbazone ligands derived from 3-bromo-5-chloro-2-hydroxy-benzaldehyde. The complexes were characterized by physicochemical and spectroscopic methods. In addition, their molecular structures were determined by single-crystal X-ray diffraction. In both complexes, the Ni atom has a near square-planar geometry, being coordinated by the phenolato oxygen, azomethine nitrogen and amine nitrogen atoms of the thiosemicarbazone ligands, together with the phosphorus atom of the triphenylphosphine. The S-methyl complex includes an additional free thiosemicarbazone ligand in the asymmetric unit. X-ray analysis shows that O-HN, N-HN, C-HN and C-HO-type hydrogen bonds and - stacking interactions are responsible for stabilizing the crystal structures. | |
dc.language.iso | eng | |
dc.subject | Kimya | |
dc.subject | KİMYA, İNORGANİK VE NÜKLEER | |
dc.subject | Temel Bilimler | |
dc.subject | İnorganik Kimya | |
dc.subject | Temel Bilimler (SCI) | |
dc.title | Hydrogen-bonded and -stacked nickel(II) thiosemicarbazone complexes: Synthesis, spectral and structural studies | |
dc.type | Makale | |
dc.relation.journal | TRANSITION METAL CHEMISTRY | |
dc.contributor.department | Istanbul University - Cerrahpasa , , | |
dc.identifier.volume | 44 | |
dc.identifier.issue | 2 | |
dc.identifier.startpage | 115 | |
dc.identifier.endpage | 123 | |
dc.contributor.firstauthorID | 647559 | |