dc.contributor.author | Senol, A | |
dc.date.accessioned | 2021-03-06T08:39:24Z | |
dc.date.available | 2021-03-06T08:39:24Z | |
dc.identifier.citation | Senol A., "Liquid-liquid equilibria for the system (water plus carboxylic acid plus chloroform): Thermodynamic modeling", FLUID PHASE EQUILIBRIA, cilt.243, ss.51-56, 2006 | |
dc.identifier.issn | 0378-3812 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_e2053893-1fe0-471f-891e-cc64376e85f6 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/148790 | |
dc.identifier.uri | https://doi.org/10.1016/j.fluid.2006.02.017 | |
dc.description.abstract | Liquid-liquid equilibrium (LLE) data of the solubility curves and tie-line end compositions are presented for mixtures of [water (1) + acetic acid, or pyruvic acid, or valeric acid (2) + chloroform (3)] at T = 293.15 K and atmospheric pressure. Among the studied ternary systems, the largest separation factors give valeric acid. A solvation energy relation (SERLAS) has been used to estimate the liquid-liquid equilibria of associated systems containing a protic solvent. The tie-lines were also predicted through the UNIFAC-original model. The reliability of both models has been analyzed against the LLE data with respect to the distribution ratio and separation factor. SERLAS matches LLE data relatively accurately, yielding a mean error of 18.5% for all the systems considered. (c) 2006 Elsevier B.V. All rights reserved. | |
dc.language.iso | eng | |
dc.subject | Kimya Mühendisliği ve Teknolojisi | |
dc.subject | Fizikokimya | |
dc.subject | Temel Bilimler | |
dc.subject | Mühendislik ve Teknoloji | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | MÜHENDİSLİK, KİMYASAL | |
dc.subject | Kimya | |
dc.subject | KİMYA, FİZİKSEL | |
dc.subject | Mühendislik, Bilişim ve Teknoloji (ENG) | |
dc.subject | Mühendislik | |
dc.subject | TERMODİNAMİK | |
dc.title | Liquid-liquid equilibria for the system (water plus carboxylic acid plus chloroform): Thermodynamic modeling | |
dc.type | Makale | |
dc.relation.journal | FLUID PHASE EQUILIBRIA | |
dc.contributor.department | , , | |
dc.identifier.volume | 243 | |
dc.identifier.startpage | 51 | |
dc.identifier.endpage | 56 | |
dc.contributor.firstauthorID | 178491 | |