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dc.contributor.authorOnar, Hulya Celik
dc.contributor.authorHasdemir, Belma
dc.contributor.authorYusufoglu, Ayşe Sergüzel
dc.date.accessioned2021-03-02T23:12:15Z
dc.date.available2021-03-02T23:12:15Z
dc.date.issued2007
dc.identifier.citationOnar H. C. , Hasdemir B., Yusufoglu A. S. , "Asymmetric Meerwein-Ponndorf-Verley reduction of long chain keto alkanoic acid methyl esters", JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, cilt.72, sa.5, ss.421-427, 2007
dc.identifier.issn0352-5139
dc.identifier.otherav_1109615e-f9bb-4c55-b622-b1f294ea221d
dc.identifier.othervv_1032021
dc.identifier.urihttp://hdl.handle.net/20.500.12627/16952
dc.identifier.urihttps://doi.org/10.2298/jsc0705421o
dc.description.abstract3-, 7- and 13-Monoketo tetradecanoic acid methyl esters carrying a keto group at the ends and at the middle of the chain with 14 carbon atoms were reduced by a Meerwein-Ponndorf-Verley reaction in the presence of R-(+)-1,1'-binaphthalcne-2,2'-diol, 1,2:5,6-D-di-O-isopropylidene-D-mannitol and L-(-)-menthol. The highest enantiomeric purity of 65% ee was found for 13-hydroxy ester isomer. The enantiomeric excess was determined by H-1-NMR shift with Eu(tfc)(3) and by optical rotation.
dc.language.isoeng
dc.subjectTemel Bilimler (SCI)
dc.subjectAlkoloidler
dc.subjectKİMYA, MULTİDİSİPLİNER
dc.subjectKimya
dc.subjectBiyokimya
dc.subjectTemel Bilimler
dc.titleAsymmetric Meerwein-Ponndorf-Verley reduction of long chain keto alkanoic acid methyl esters
dc.typeMakale
dc.relation.journalJOURNAL OF THE SERBIAN CHEMICAL SOCIETY
dc.contributor.department, ,
dc.identifier.volume72
dc.identifier.issue5
dc.identifier.startpage421
dc.identifier.endpage427
dc.contributor.firstauthorID6478


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