dc.contributor.author | Sebin, Merve Ece | |
dc.contributor.author | Koc, Serkan Naci | |
dc.contributor.author | Akmaz, Solmaz | |
dc.date.accessioned | 2021-03-02T16:06:00Z | |
dc.date.available | 2021-03-02T16:06:00Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Sebin M. E. , Akmaz S., Koc S. N. , "Hydrogenation of furfural to furfuryl alcohol over efficient sol-gel nickel-copper/zirconia catalyst", JOURNAL OF CHEMICAL SCIENCES, cilt.132, sa.1, 2020 | |
dc.identifier.issn | 0974-3626 | |
dc.identifier.other | av_771e9823-6d87-4d77-9bbb-918252632b74 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/2293 | |
dc.identifier.uri | https://doi.org/10.1007/s12039-020-01859-1 | |
dc.description.abstract | Furfuryl alcohol (FA), a valuable compound from furfural (FF) was synthesized by efficient Ni-Cu/ZrO2 catalysts. The catalysts with varying Ni and Cu loading were developed by sol-gel method and characterized by Brunauer-Emmet-Teller (BET) method, X-ray diffraction, Temperature Programmed Reduction (TPR), X-ray photoelectron spectroscopy techniques. Cu/ZrO2 and Ni/ZrO2 catalysts were also tested to compare the effect of the Ni-Cu/ZrO2 catalyst. Both Ni and Cu showed the synergistic effect on FA formation. The Ni-Cu/ZrO2 catalyst was used for hydrogenation of FF by changing pressure, catalyst loading, temperature and time. A 93% FA yield was achieved over the 7Ni-Cu/ZrO2 catalyst with 0.07 g Ni and 0.1 g Cu/1 g ZrO2 at 200 degrees C for 4 h under 1.5 MPa H-2 pressure. The sol-gel Ni-Cu/ZrO2 catalyst without the use of expensive noble metals is effective on the hydrogenation of FF to FA relatively in mildly reaction pressure. Graphic abstract The Ni-Cu/ZrO2 catalyst was used for hydrogenation of FF by changing pressure, catalyst loading, temperature and time. A 93% FA yield was achieved over the 7Ni-Cu/ZrO2 catalyst with 0.07 g Ni and 0.1 g Cu/1 g ZrO2 at 200 degrees C for 4 h under 1.5 MPa H-2 pressure. The sol-gel Ni-Cu/ZrO2 catalyst without the use of expensive noble metals is effective on the hydrogenation of FF to FA relatively in mildly reaction pressure. | |
dc.language.iso | eng | |
dc.subject | Physical Sciences | |
dc.subject | Temel Bilimler | |
dc.subject | General Chemistry | |
dc.subject | Chemistry (miscellaneous) | |
dc.subject | Alkoloidler | |
dc.subject | Biyokimya | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | Kimya | |
dc.subject | KİMYA, MULTİDİSİPLİNER | |
dc.title | Hydrogenation of furfural to furfuryl alcohol over efficient sol-gel nickel-copper/zirconia catalyst | |
dc.type | Makale | |
dc.relation.journal | JOURNAL OF CHEMICAL SCIENCES | |
dc.contributor.department | Istanbul Univ Cerrahpa , , | |
dc.identifier.volume | 132 | |
dc.identifier.issue | 1 | |
dc.contributor.firstauthorID | 2371057 | |