dc.contributor.author | TÜRKER, GÜLEN | |
dc.contributor.author | Yusufoglu, Ayşe Sergüzel | |
dc.date.accessioned | 2021-03-02T21:03:44Z | |
dc.date.available | 2021-03-02T21:03:44Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | TÜRKER G., Yusufoglu A. S. , "Asymmetric Reduction of Monoketo Hexadecanoic Acid Methyl Esters", ASIAN JOURNAL OF CHEMISTRY, cilt.25, sa.3, ss.1531-1535, 2013 | |
dc.identifier.issn | 0970-7077 | |
dc.identifier.other | vv_1032021 | |
dc.identifier.other | av_0540e767-4b6d-4cc5-88fa-b5228ef258a9 | |
dc.identifier.uri | http://hdl.handle.net/20.500.12627/9409 | |
dc.description.abstract | Methyl 2-,3-,6-,8-,14- and 15-keto hexadecanoates were reduced by using NaBH4 in presence of 1,2;5,6-di-O-isopropilydene-D-glucofuranose [DIPGH], R(+)-1,1'-binaphthyl-2,2'-diol [RBND] and pivalic acid [PA]. The reduction of 2- and 3-keto esters in the presence of (+)-1,1'-binaphthyl-2,2'-diol results in considerably higher stereoselectivities (95 % ee). Enantiometric excess (ee %) was determined by H-1 and C-13 NMR analyses using a shift reagent, Eu(tfc)(3). | |
dc.language.iso | eng | |
dc.subject | Biyokimya | |
dc.subject | Alkoloidler | |
dc.subject | Temel Bilimler | |
dc.subject | Temel Bilimler (SCI) | |
dc.subject | Kimya | |
dc.subject | KİMYA, MULTİDİSİPLİNER | |
dc.title | Asymmetric Reduction of Monoketo Hexadecanoic Acid Methyl Esters | |
dc.type | Makale | |
dc.relation.journal | ASIAN JOURNAL OF CHEMISTRY | |
dc.contributor.department | Çanakkale Onsekiz Mart Üniversitesi , Çanakkale Uygulamalı Bilimler Yüksekokulu , Gıda Teknolojisi | |
dc.identifier.volume | 25 | |
dc.identifier.issue | 3 | |
dc.identifier.startpage | 1531 | |
dc.identifier.endpage | 1535 | |
dc.contributor.firstauthorID | 6509 | |